Synthesis of Novel Chiral C 2-symmetric Diaza-18-crown-6 Ether Derivatives and their Enantioselective Recognition of Amino Acid Derivatives

New chiral diaza-18-crown-6 ether derivatives, 5 and 6 were synthesized from (R)-(-)-2-amino-1-bütanol. These chiral artificial receptors exhibit pronounced chiral recognition toward the enantiomers of l- and d- amino acid derivatives. The highest enantioselectivity was observed in the case of Trp-OMe·HCl (K_D/K_L=12.5).     

On the operations of sequences in rings and binomial type sequences

Given a commutative ring with identity R, many different and interesting operations can be defined over the set \(H_R\) of sequences of elements in R. These operations can also give \(H_R\) the structure of a ring. We study some of these operations, focusing on the binomial convolution product and the operation induced by the composition of exponential generating functions. We provide new relations between these operations and their invertible elements. We also study automorphisms of the Hurwitz series ring, highlighting that some well-known transforms of sequences (such as the Stirling transform) are special cases of these automorphisms. Moreover, we introduce a novel isomorphism between \(H_R\) equipped with the componentwise sum and the set of the sequences starting with 1 equipped with the binomial convolution product. Finally, thanks to this isomorphism, we find a new method for characterizing and generating all the binomial type sequences.

     

On minimal non-M_rC-groups

A group $G$ is said to be a minimax group if it has a finite series whose factors satisfy either the minimal or the maximal condition. Let $D(G)$ denotes the subgroup of $G$ generated by all the Chernikov divisible normal subgroups of $G$ . If $G$ is a soluble-by-finite minimax group and if $D(G)=1$ , then $G$ is said to be a reduced minimax group. Also $G$ is said to be an $ M_{r}C$ -group (respectively, $PC$ -group), if $G/C_{G} \left(x^{G}\right)$ is a reduced minimax (respectively, polycyclic-by-finite) group for all $x\in G$ . These are generalisations of the familiar property of being an $FC$ -group. Finally, if $\mathfrak X $ is a class of groups, then $G$ is said to be a minimal non- $\mathfrak X $ -group if it is not an $\mathfrak X $ -group but all of whose proper subgroups are $\mathfrak X $ -groups. Belyaev and Sesekin characterized minimal non- $FC$ -groups when they have a non-trivial finite or abelian factor group. Here we prove that if $G$ is a group that has a proper subgroup of finite index, then $G$ is a minimal non- $M_{r}C$ -group (respectively, non- $PC$ -group) if, and only if, $G$ is a minimal non- $FC$ -group.     

Influence of Musa acuminate bio-filler on the thermal,mechanical and visco-elastic behavior of poly (propylene) carbonate biocomposites

Biocomposites were fabricated using poly(propylene) carbonate as matrix and cellulosic polysaccharide banana (Musa acuminate) peel powder as filler in varying concentrations (5–25?wt.%) and were characterized for their functional properties. Microscopic analysis indicated the uniform distribution and existence of microfibrils in the filler. The thermal stability of the composites was lower than the matrix till 320?°C, beyond which it increased. The visco-elastic and mechanical behavior of the biocomposites was found to be enhanced with the addition of fillers. Thus, with better thermal, visco-elastic, and mechanical properties, the biocomposite films can be a replacement for the non-biodegradable polymers for packaging applications.     

Large spectral tuning of a water-glycerol microdroplet by a focused laser: characterization and modeling

Large spectral tuning of a water-glycerol microdroplet standing on a superhydrophobic surface by local heating with a focused infrared laser is studied both experimentally by optical spectroscopy and computationally using a lumped system formulation of the mass and heat transfer between the microdroplet and the chamber. The effects of optical scattering force, chamber humidity, size of microdroplet and laser power on the tuning mechanism are examined. The reversibility of the tuning mechanism is also studied. In spite of its negligibly small volatility compared to that of water, irreversibility is found to be mainly caused by evaporation of glycerol. It is also found that reversibility increases dramatically with the relative water and glycerol humidities, and spectral tuning can be made almost fully reversible when the chamber is saturated with glycerol vapor and the relative water humidity approaches unity. Some hysteresis effects are observed, especially in large microdroplets, and this behavior is attributed to the whispering-gallery mode resonances in laser absorption. The time response of the tuning mechanism is also analyzed both experimentally and computationally. The technique presented can find applications in optical communication systems, and can be used in fundamental studies in cavity quantum electrodynamics and in characterizing liquid aerosols on a surface.     

Controlled observation of nondegenerate cavity modes in a microdroplet on a superhydrophobic surface

We demonstrate controlled lifting of the azimuthal degeneracy of the whispering gallery modes (WGMs) of single glycerol-water microdroplets standing on a superhydrophobic surface by using a uniform electric field. A good agreement is observed between the measured spectral positions of the nondegenerate WGMs and predictions made for a prolate spheroid. Our results reveal fewer azimuthal modes than expected from an ideal spherical microdroplet due to the truncation by the surface. We use this difference to estimate the contact angles of the microdroplets.     

Inner-sphere oxidation of cis-diaquabis(oxalato)chromate(III) by periodate in aqueous weakly acidic solutions

The kinetics of oxidation of cis-[Cr^III(ox)₂(H₂O)₂]^– (ox = C₂O₄ ^2–) by IO₄ ^– showed a first-order dependence on the initial Cr^III complex concentration in the presence of a vast excess of [IO₄ ^–]. The dependence of the pseudo-first-order rate constant on [IO₄ ^–] is complex and is consistent with the formation of a precursor complex. It is proposed that this complex is formed through the coordination of the two carbonyl oxygens of the ox ligand with the IO₄ ^– ion, forming a cyclic intermediate. The kinetics are consistent with the hydroxo form of the Cr^III complex being the reactive species, whereas the aqua species forms an unreactive complex.     

Facile synthesis of Cu-LDH with different Cu/Al molar ratios: application as antibacterial inhibitors

Research on Chemical Intermediates - A range of Cu-LDHs has been synthesized by co-precipitation using metal nitrate precursors and sodium carbonate under varying molar ratios Cu/Al...